Ludwig Boltzmann described the concept of entropy on the molecular level. What can we conclude about the entropy change of the surroundings?Ģ3 19.3 The Molecular Interpretation of Entropy These last truths mean that as a result of all spontaneous processes the entropy of the universe increases.Ģ2 19.2 GIST How do we reconcile the fact that S is a state function but that ∆S depends on q, which is not a state function? The rusting of iron is accompanied by a decrease in the entropy of the system (the iron and oxygen). In other words: For reversible processes: Suniv = Ssystem + Ssurroundings = 0 For irreversible processes: Suniv = Ssystem + Ssurroundings > 0 The second law of thermodynamics states that the entropy of the universe increases for spontaneous processes, and the entropy of the universe does not change for reversible processes. What is the change in entropy in the system when 68.3 g of C2H5OH(g) at 1 atm condenses to liquid at the normal boiling point? What is the entropy change of the system when 50.0 g of Hg(l) freezes at the normal freezing poing?ġ8 Practice The normal boiling point of ethanol, C2H5OH, is 78.3✬, and its molar enthalpy of vaporization is kJ/mol. The normal freezing point of mercury is -38.9✬, and its molar enthalpy of fusion is ΔHfus = 2.29 kJ/mol. S = qrev Tġ7 Sample Exercise 19.2 The element mercury, Hg, is a silvery liquid at room temperature. Therefore, S = Sfinal Sinitialġ6 Entropy For a process occurring at constant temperature (an isothermal process), the change in entropy (ΔS) is equal to the heat that would be transferred if the process were reversible (qrev) divided by the temperature: Can be used to calculate ΔS for phase changes. It is related to the various modes of motion in molecules.ġ5 Entropy Like total energy, E, and enthalpy, H, entropy is a state function. Clausius was convinced of the significance of the ratio of heat delivered and the temperature at which it is delivered q Tġ4 Entropy Entropy can be thought of as a measure of the randomness of a system. Spontaneous processes are irreversibleġ1 19.1 GIST If a process is nonspontaneous, does that mean the process cannot occur under any circumstances? If you evaporate water and then condense it, have you necessarily performed a reversible process?ġ2 19.2 Entropy and the Second Law of Thermodynamicsġ3 Entropy Entropy (S) is a term coined by Rudolph Clausius in the 19th century. Irreversible processes cannot be undone by exactly reversing the change to the system. Is the transformation of CO2(s) to CO2(g) a spontaneous process at -100✬ and 1 atm pressure.ĩ Reversible Processes In a reversible process the system changes in such a way that the system and surroundings can be put back in their original states by exactly reversing the process. Below 0 C the reverse process is spontaneous.ħ Sample Exercise 19.1 Predict whether the following processes are spontaneous as described, spontaneous in the reverse direction, or in equilibrium: A) When a piece of metal is heated to 150✬ is added to water at 40✬ B) Water at room temperature decomposes into H2(g) and O2(g) C) Benzene vapor, C6H6(g), at a pressure of 1 atm condenses to liquid benzene at the normal boiling point of benzene, 80.1✬Ĩ Practice Under 1 atm pressure, CO2(s) sublimes at -78✬. Above 0 C it is spontaneous for ice to melt. Processes that are spontaneous at one temperature may be nonspontaneous at other temperatures. Processes that are spontaneous in one direction are nonspontaneous in the reverse direction. The gas in vessel B will spontaneously effuse into vessel A, but once the gas is in both vessels, it will not spontaneously return to vessel B. Spontaneous processes are those that can proceed without any outside intervention. Energy can, however, be converted from one form to another or transferred from a system to the surroundings or vice versa. Therefore, the total energy of the universe is a constant. You will recall from Chapter 5 that energy cannot be created nor destroyed.
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Download the electronic version (PDF, 10.6 Mo) Order paper version. These are the subjects you will need to learn. Each state has a number of DMV handbooks and drivers manuals to help you become a safer driver. It is also intended for all stakeholders in the goods and passenger transportation industry who play a role in heavy vehicle maintenance and road safety. Curious about the content in the theory book? The more questions you answer correctly, the higher your chances of success. It covers all the essential driving skills right from learning how to drive to understanding road signs. and drivers who want to brush up on their knowledge. This comprehensive test allows you to assess your readiness for the official exam. Oh, and dont forget to take our free BC Driving Practice Test before attempting the real written exam This BC drivers handbook online is for learners, new residents to B.C. Once you have finished studying the theory, it’s time to put your knowledge to the test with the pre-exam test in the Exercises book. The theory book covers a wide range of topics with the help of photos, cartoons, and illustrations, making it easier to grasp the rules and concepts. The theory book and exam training book included in this package are direct translations of the Belgian books, ensuring that you receive accurate and up-to-date information.
Here is a list of standard poster sizes ISO from Wikipedia. Some printers can print larger poster size, but that will depend if it is a digital printer or other kind of printer capable to print large documents. There are some ISO format sizes for posters which you may choose from as well as other custom poster sizes available. Here is a list of poster sizes available for you to use. Also, other roll sizes are 24”, 36” and 42”, so it is best to set either the height or width of your poster to one of these measurements. Important: The printer’s maximum size paper roll is 44”, meaning that one of your dimensions, width or height, may not exceed 44”. The poster’s size will be doubled during the printing phase to bring it up to 44×66 inches as desired. For example, for a 44” x 66” poster, you would enter 22” in the box for height and 33” in the box for width, and click OK. Please be aware that PowerPoint’s maximum size is 52” therefore to produce a PowerPoint poster with dimensions larger than 52”, both dimensions are entered at half the desired size. Depending on the printer and place where you want to show your poster, you’d choose from one poster size or the other.Įnter the Height and Width of your poster. Poster frames have different poster sizes that vary from a wide range of options. And don’t forget to set it as landscape if you want it horizontally. Then you can enter a custom poster size, for example 48″ width x 18″ height. Once you find the Design tab, then click on Page Setup option and you will be prompted to choose a Slide size. Once we start a new PowerPoint presentation we need to find the Design tab on top in Microsoft PowerPoint (in previous versions of PowerPoint there was a Page Setup option under File menu). If you want to create a PowerPoint poster presentation from scratch then making a new PowerPoint presentation is a good starting point. How to create a Poster in Microsoft PowerPoint? If you want to try finding the poster template you can start browsing for poster templates in this gallery.īut sometimes these poster templates aren’t useful because you need a different format or layout. You can get free Poster PowerPoint templates by browsing the Office template gallery. So many fond memories with this game, i remember when i used to live in Mexico that my cousin gave me this game so i could play it. Sun 1st Mar man, this game is my favorite game of all time, period.Nothing in SMG really seems to match up for me. I don't know why, and I know SMG's music is well-orchestrated, but maybe it's just the nostalgia that gets me. I got Mario's 120 stars and whatnot, and some of the level design is good, but somehow I just feel like it doesn't have that soul that Super Mario 64 does.Īll those castle rooms, jumping through paintings, Bowser's laugh, the infinite staircase, Metal Mario, the Wing Cap, aspiring to enter that damn cannon and reach the top of the castle, racing the penguin and throwing the babies off ledges and into the chimney, finding secret teleports and fake walls. I think SMG is fun and all, but I guess I'm missing something. Some people are saying Super Mario Galaxy is better than this game. Not to mention, having two small screens kind of made it lose some of the magic. The game was simply designed for the N64 controller, and it just does not work on the DS. Unfortunately, they didn't have too much to offer and were usually only a boss or a star's length. The few extra worlds there were I liked, they were neat. The new mini-games were mostly good, especially at launch, but the extra 30 stars weren't really all that spectacular and some of the changes kill a bit of the nostalgia. Also, as much as I always wanted Luigi and Wario in that castle (and Yoshi, but I wanted to ride him.), I felt it just complicated things and subtracted from it. I didn't like how they tried to make the graphics more detailed, it just came off as looking ugly. Just like Animal Crossing, I thought having a ton of new stuff would make it better than ever, but the original Super Mario 64 is just better. Also, game works much much better with the Gamecube controller than with the Classic.ĭownload it if you don't already have it on a working N64 - otherwise, it's not that different and you can spend your points for something you don't have. Why does so much of the game move like the surfaces are covered with ice, no matter what the surface Mario's running on? Sand, grass, 's all way too slippery.Īside from that (which is a BIG detraction for me - makes the game seem unpolished and goofy) the game is pretty much a fun fest. Same for some of the coins that he's collecting from the enemies. He slips and falls WAY too much and when he does there are nutty sliding physics in the game that go on for WAY too long. I have always wondered how everyone can play this and not notice that Mario always moves like the entire playing field has been covered with oil. How we loved abusing the mistakes of hapless programmers.Ī great game that I originally had on my Funtastic orange N64.Ĭontrols are a bit wonky however. If you can do all this fast enough and in the right order, you can cheat the game. You can do the same thing up the 'never-ending' looping stairs to the Bowser in the Sky course. The bunny trick, you ask? Well, you remember that one bunny in the basement that gives you a star when you catch it? If you pick it up again, you can carry it around, and if you set it against a doorway just right, it will push Mario through doors he shouldn't technically be able to open yet.Īnd the backwards long jump stairs? Once you get to the 3rd floor, you can start a long jump in front of the stairs to the 4th floor, facing away from them, and then long jump backwards up the stairs and through the door. The biggest parts of this kind of speed run were the bunny trick and the backwards long jump stairs. If they were, i have to admit it'd be a shame. I wonder if it's still possible on the VC, or if the glitches were fixed. I only ever managed to do it twice, though. We actually figured out that you could exploit a couple of glitches to beat the game in about 20 minutes with only 16 stars, if you were good enough. I remember playing it for hours on end as a kid. Dribbleĭribble is not meant to be your online portfolio. It also works like a social media network where you can follow your favourite authors, create mood boards, and appreciate other portfolio websites. On Behance, you can only build a one-page portfolio website, but you can upload unlimited projects to it. That’s because you can navigate Behance’s job list and apply using your profile and portfolio. It’s completely free to use, and – unlike Adobe Portfolio – you don’t need to have an Adobe membership.īehance is one of the best portfolio websites to meet potential clients and find creative jobs. Behanceīehance is a platform created by Adobe where you can display your work and connect with other creators. You’ll be assigned a personal domain name, but you can also buy a custom domain and connect it with your portfolio page. You can protect single pages or the entire website with a password, and you can create up to five different websites optimised for any device. There’s a Behance and Lightroom integration, so you can easily import your projects and keep your portfolio updated. The platform is very easy to use, and you can customise your own photography website by adding blocks of images, text, contact forms, etc. You can choose between creating a landing page or a portfolio site with multiple pages. So, if you already use an Adobe app for your graphic design process or your photography projects, you can have a free portfolio website. Adobe PortfolioĪll Creative Cloud subscriptions include Adobe Portfolio. They are a great way to start a portfolio website while you grow your business enough to start investing. Most free portfolio websites can upgrade to a paid membership that gives you additional features, capability, or an ad-free version. The best portfolio websites listed below allow you to create and manage a free account for your photography or design portfolio. Photo editing in Google Photos is fairly limited, but you can quickly apply filters and tweak elements such as brightness and contrast, all of which are reversible, even if you come back to the photo much later. This allows you to perform a search for an object contained within the actual image itself, making keywording and tagging individual photos a chore of the past. Having all of your images stored in Google’s cloud platform means that Google Photos can take advantage of sophisticated search capabilities, not simply using keywords and other data stored in your images, but also Google’s intelligence to identify what’s in your photos. Google Photos allows you to store and synchronise your images automatically - for free if you choose to make a small compromise on the resolution, although this is due to change in the summer of 2021. Rather than being installed on your computer, Google Photos is a web-based application that works a little differently. With the retirement of Picasa, many hoped that Google Photos would prove to be a good alternative, and it certainly comes close. See our in-depth Lightroom Classic review here, or click the button above to start a free trial. It’s easy to browse a vast catalogue of images with relative ease, making Lightroom one of the best Google Picasa alternatives if you have the budget for it. Lightroom’s file management features are powerful, offering keywords, sophisticated filtering and sorting. There’s a standalone version (“Classic”) for Windows and MacOS machines, and there’s a “CC” version that also works on mobile devices, allowing you to synchronise your work while keeping your archive in the cloud. Presets allow you to perform rapid edits and synchronise changes across any number of images. It might not (yet) contain the AI features of something like Luminar 4, but Adobe Lightroom has an extensive array of tools for processing images.īasic changes can be applied quickly and easily, and you can then choose to create more complex edits using local adjustments and color grading tools. Lightoom is the choice of professional photographers around the world, and for good reason. See our full review of Luminar here, or click the button above to download it today.Īdobe has been the industry standard for image editing for decades and Lightroom is a powerful piece of software that has evolved alongside digital cameras. However, it’s definitely one of the best choices when it comes to editing your photos, so in that sense, it’s definitely a top Picasa alternative. In addition, Luminar can swap out a sky, make an unwanted part of an image disappear, smooth the skin and enhance the eyes on a portrait - all within just a few clicks.īecause of the emphasis on editing, Luminar is not well suited to managing a large number of files and doesn’t support features such as facial identification, keywords, or collections. Luminar takes advantage of AI machine learning to offer automatic edits to your photographs, making suggestions based on millions of existing photographs. While you can get very technical in your edits using things like masking and layers, Luminar 4 is best-known for its use of AI. Luminar is geared towards editing individual photographs and puts a lot of power in your hands. Luminar Neo is one of the most powerful, fully-featured pieces of editing software available on the market in 2024, offering one-click editing solutions while also allowing you to dig deep into an image to create a distinctive look. In 1993, he established a Dallas single-season record for tackles by a defensive back (155). In 1995, he became the first Dallas defensive back to lead the team in tackles (144) since Bill Bates in 1988. He also went over the 100 tackle mark in four consecutive seasons (1993-96), becoming the first Dallas player to accomplish that feat since Michael Downs (1983-86). Woodson finished first or second on the team in tackles in five of the last 11 seasons (1993-96, 1998). Woodson maintained the aggressive nature that he displayed as a college linebacker, but used his quickness and speed to make a very smooth transition to the secondary. With 23 career interceptions, Woodson closed his career out 10th on the club's all-time list. Woodson had 48 double-figure tackle games in his career, and in 2002, he became the leading tackler in Dallas Cowboys history by passing Lee Roy Jordan (1,236) stops. He started 175 of 194 career games during his playing career, including playoffs, missing only 14 possible games during the entirety of his career. He recorded at least 100 tackles in nine of his 12 seasons. He combined size (6-1, 219) and speed (4.4 in the 40-yard dash) with great football instincts and hitting ability. He was inducted as the 21st member of The Dallas Cowboys Ring of Honor on Novemat halftime of the Cowboys-Seahawks game.Ī converted college linebacker from Arizona State, Woodson became the complete NFL package at safety. Woodson's four All-Pro selections tied him with Mel Renfro (1965, 1967, 19) and Cliff Harris (1975-1978) for the most All-Pro selections by a safety in team history. He was selected to five Pro Bowls, was named first team All-Pro four times and played in three Super Bowls. In addition, his versatility at playing both the run and pass at an extremely productive level is what separated Woodson from the rest of the strong safety field. Woodson's dependability, athleticism, aggressiveness and the ability to produce in the big game put him in the elite level of performers in the NFL. Throughout his career, Woodson clearly and consistently established himself as one of the NFL's premier strong safeties. Along the way, he helped Dallas win three Super Bowl championships, securing an elite position in the club's history. After 12 years of service, Darren Woodson retired following the 2003 season as the Cowboys all-time leading tackler (1,350 career stops). Mention how you created new hiring plans, optimized workplace practices, and nurtured a supportive work environment. When applying for a managerial role, it’s important to highlight instances when you’ve owned more complex tasks.Don’t worry: Not everything you trim away to keep your resume to a single page has to be gone forever! If you had some points that were simply too good to part with, like that time you skyrocketed employee satisfaction rates, they may be useful in your HR cover letter.Any longer than a page, whatever you included on page two will likely go unread if your resume isn’t simply discarded in favor of a more concise one. Your resume should be one page or less, making it easy for a recruiter to skim your highest points, such as your own chops regarding recruiting or your ability to forecast for full-time hiring needs.What impact did they have? Did your work improve employee retention? Reduce onboarding time? Still not totally sure how to present your soft skills with good metrics? If you start to feel like you’re just listing random numbers, step back and look for how they tie into your profession.If you’re asking yourself “How much is too much?” remember: Stick with a modern resume template with two colors maximum, and always use clear, readable fonts. It’s always good to look approachable but professional on your HR manager resume.Top 5 Tips for Your Human Resources Manager Resume Collected job requirements and posted 53 job descriptions on internal and external sites, acquiring 8 full-time hires within a month.Led forecasting for yearly full-time and contractor recruitment needs with 27 company executives, increasing team efficiency and elevating employee satisfaction by 14%.Identified gaps in interview funnel and recommended proactive changes that improved average time-to-hire by 18%.Gathered feedback after final interviews, boosting positive reviews on Glassdoor to 4.8/5 stars.The summary should focus on the specific. You must also include a professional career summary. Here are some sample work experience bullet points: Powerful Summary for Chief Human Resources Officer (CHRO) Resume. While providing metrics like percentages and improvements in ratings, you also want to exhibit a trend of advancement throughout your experience section. Our sample HR Director rsum incorporates best practice ideas on how to write an HR-specific career profile, based on our analysis of the many hundred. This can get tricky while featuring soft skills, but look for ways to go beyond what you did to show the measurable impact it had. You’ll have to back up your claims with quantifiable data, too. Recruiters want to know what you accomplished and how. While your skills show what you can do, your work history shows how you put them into practice. Sample human resources manager work experience bullet points Your product name is mentioned in the top right-hand corner, as shown in the screenshot below.Press the HOME button on the supplied remote control.Select System information, as shown in the screenshot below.Menu path for other Android TVs (e.g. 2017 XE90) In this view, navigate to System information, then press OK on the remote.Navigate to Status & Diagnostics on the left side of the screen, then press OK on the remote.Press the Help button on the supplied remote control.TIP: How to tell the difference between an Android and non-Android TVĪndroid TV/Google TV Menu path for the Android TVs /Google TVs listed below.The Date of manufacture (e.g., 2023/05).ĭepending on whether your TV is an Android TV or not, the procedure may vary slightly.(e.g., 5501771), which can also be found on the original box/packaging. If there is no sticker on the left side of the back of your TV, check the terminal sticker on the right side, as in the pictures below. The Part number (P/N - this number is for internal purposes only).The 7-digit Serial number or S/N (e.g., 6000027), which can also be found on the original box/packaging.On the sticker, you will find the following information: Look for a small, black-and-white sticker on the bottom left side of the back of your TV, as shown in the picture below. your TV is wall-mounted), go to the next option: Check the Settings menu. If you can't check the serial number sticker (e.g.The sticker location might differ depending on your TV model.Please tell me a good website where I can buy Windows keys. I've been looking for a reliable source of windows 10 keys for ages! If there's a site that has all of the above features then I would be stoked if someone could let me know what it is. Responsive customer support incase I have an issue.I will likely be needing to buy multiple keys as I have been building some custom gaming PC's for clients of mine. Having to wait for someone to send it manually is just a red flag in my eyes and sites like that should be avoided at all costs. It's a virtual product so the key should just instantly deliver to me email. I also don't want to be waiting around for the product key to be delivered either. The only issue is trying to get my hands on a windows key that is retail and not OEM or a MaK volume license key. I know that the source of a retail key doesn't matter because they are retail and perfectly legal for resale. I want a key that is legal in case of a software audit. Note that I want to avoid getting an OEM key. I know that you can get cheap windows keys because I've used sites in the past where I was able to get them for like $30 and they worked perfectly fine. G2A and Kinguin (avoid these two sites).Subreddits such as windows 10 key reddit, windows 10 product key reddit, reddit windows keys, reddit windows key.Places I've tried to get a windows key but failed Please don't tell me to pirate windows either because I have gotten malware in the past trying to do that. I've tried some other sites that didn't have PayPal as a payment processor and I never got my money back for my faulty key. Then I know that if my key doesn't work I can just launch a chargeback. I preferably want to use a site that has a reputable payment processor such as PayPal. I've lost about $30 in total by trying to by windows product keys from users on certain subreddits but they've never ended up sending me my key. I want to use a windows key site that is trustworthy. I don't want to get one on reddit because I've been left empty handed by some people who sell on a sub reddit before. I was wondering on where to get a legit windows 10 key. Note: many websites do not allow their pages to be rendered in an iframe (This is mediated via a X-Frame-Options HTTP response header ). Popular web applications which make use of this feature including Google Docs & Spreadsheets (formerly Writely), JotSpot Live, and Windows Live Hotmail to name a few. However, Mozilla Firefox, Opera and Microsoft Internet Explorer introduced contentEditable and designMode, which enables users to edit the contents of the HTML contained in an IFrame. In these activities iframe-embedded video displays in the HTML editor, but will be stripped out when posts or submissions are saved.Ĭaution: not all browsers recognize IFrame. In general, iframe code is not allowed in Moodle activities to which all class members can contribute, including Assignment submissions, Wiki, Forum, Database, Glossary, and Blog activities. On the other hand, the IFrame can contain its own scroll bar, independent of the surrounding page's scroll bar.įor security reasons, moodle just does not allow you to use iframes everywhere. The IFrame behaves much like an inline image and the user can scroll it out of view. The size of the IFrame can be specified in the surrounding HTML page, so that the surrounding page can already be presented in the browser while the IFrame is still being loaded. NOTE: Screen widths are often 1200 pixels wide so an iFrame up to 1000 pixels is often fine.
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